Anya/Spike
I usually get scolded, but I'm an Anya/Spike shipper all the way. I always thought they had chemistry, and I've never been one for the whole "opposites attract" theorum, so I think they're perfect together. I was in heaven in "Entropy", well, of course until awkwardness ensued, but of course it would, with all the Xander/Buffy baggage, but other than that, perfect couple I believe, but it's obviously not meant to be, in the Jossian sense, at least.