Xander and Anya's was more like from early S4 to the middle of S6. I think Willow's relationships have all been pretty long. We got Willow/Oz from the middle of S2 to early S4, then Willow/Tara from late S4 to early/middle S6 and her and Kennedy have been going pretty strong for a while now too, although we can't be too sure with the comic timeline.
If you count what Darla and Angelus have, they would be the ones who lasted the longest. If we count Ats couples as well, it could be the vampire couple from Hearthrob(or what the name is of the first ep in season 3).
I think Joyce and Hank might have been the longest. I guess.
Xander and Anya. Angelus and Darla, so as Spike and Drusilla, had a long relathionship, but that was only mentioned. What we saw, Xander and Anya. I like to say it's Bangel - all 7 seasons, I feel they never ended 🙂
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