I like a lot of the characters that Ursula LeGuin has developed, but especially those in the Gifts, Powers, Voices trilogy. It's not that an individual stands out but the way we get to understand and live the cast of characters.
C
caritas08
In the movie "Jane Austin Book Club" the male lead keeps trying to get his love interest to read Ursula LeGuin books. (Which she finally does). It's always made me want to read her books.