Willow and Buffy talking about Angel, Buffy explaining to Willow, what she must do in the episode "Angel."
Willow: Wow! And it is kinda novel how he'll stay young and handsome forever, although you'll still get wrinkly and die, and... Oh, and what about the children? I'll be quiet now.
Buffy: No, it's okay. I need to hear this. I need to get over him so I can...
Willow: So that you can...
Buffy: Like Xander said, I'm the Slayer, and he's a... vampire. God, I can't! He's never done anything to hurt me... Okay, no, I need to stop thinking about this. Okay, let's give another half an hour and maybe something will sink in. And then I'm going home for some major moping.
Buffy and Angel's good bye kiss in "Angel."
Angel: Look, this can't...
Buffy: ...ever be anything. I know. For one thing, you're, like, two hundred and twenty-four years older than I am.
Angel: I just gotta... I gotta walk away from this.
Buffy: I know. Me, too. One of us has to go here.
Angel: I know.
Buffy shots down Xander for a date in "Prophecy Girl."
Xander: Um... You know, Buffy, uh, Spring Fling is a... time for students to gather and... Oh, God! Buffy, I want you to go to the dance with me. You and me, on a date.
Buffy: I-I don't know what to say.
Xander: Well, you're not laughing. So that's a good start. Buffy, I like you. A lot. And I know we're friends, and we've had experiences... We've fought some blood-sucking fiends, and that's all been a good time. But I want more. I wanna dance with you.
Buffy: Xander, you're one of my best friends. You and Willow...
Xander: Well, Willow's not looking to date you. Or if she is, she's playing it pretty close to the chest.
Buffy: I don't want to spoil the friendship that we have.
Xander: Well, I don't want to spoil it either. But that's not the point, is it? You either feel a thing or you don't.
Buffy: I don't. Xander, I'm, I'm sorry. I-I just don't think of you that way.
Xander: Well, try. I'll wait.
Buffy: Xander...
Xander: Nah. Forget it. I'm not him. I mean, I guess a guy's gotta be undead to make time with you.
Buffy: That's really harsh.
vLook, I'm sorry. I don't handle rejection well. Funny! Considering all the practice I've had, huh?
Buffy: Xander, I'm sorry, I don't know...
Xander: You know what? Let's just not.
Buffy rejecting Angel in "When She Was Bad"
Buffy: So, is there danger at the Bronze? Should I beware?
Angel: I can't help thinking I've done something to make you angry. And that bothers me more than I'd like.
Buffy: I'm not angry. I don't know where that comes from.
Angel: What are you afraid of? Me? Us?
Buffy: Could you contemplate getting over yourself for a second? There's no 'us'. Look, Angel, I'm sorry if I was supposed to spend the summer mooning over you, but I didn't. I moved on. To the living.
Buffy and Angel talking about not being together in "Reptile Boy."
Angel: What are you sayin', you wanna have a date?
Buffy: No.
Angel: You don't wanna have a date?
Buffy: Who said 'date'? I-I-I never said 'date'.
Angel: Right. You just wanna have coffee or somethin'.
Buffy: Coffee?
Angel: I knew this was gonna happen.
Buffy: What? What do you think is happening?
Angel: You're sixteen years old. I'm two hundred and forty-one.
Buffy: I've done the math.
Angel: You don't know what you're doing, you don't know what you want...
Buffy: Oh. No, I, I think I do. I want out of this conversation.
Angel: Listen, if we date you and I both know one thing's gonna lead to another.
Buffy: One thing already has led to another. You think it's a little late to be reading me a warning label?v Angel: I'm just tryin' to protect you. This could get outta control.
Buffy: Isn't that the way it's supposed to be?
Angel: This isn't some fairy tale. When I kiss you, you don't wake up from a deep sleep and live happily ever after.
Buffy: No. When you kiss me I wanna die.
Buffy and Angel I love you moment in "Lie to Me".
Buffy: Who's Drusilla? And don't lie to me. I'm tired of it.
Angel: Some lies are necessary.
Buffy: For what?
Angel: Sometimes the truth is worse. You live long enough, you find that out.
Buffy: I can take it. I can take the truth.
Angel: Do you love me?
Buffy: What?
Angel: Do you?
Buffy: I love you. I don't know if I trust you.
Angel: Maybe you shouldn't do either.
Buffy: Maybe I'm the one who should decide!
Angel: I did a lot of unconscionable things when I became a vampire. Drusilla was the worst. She was... an obsession of mine. She was pure and sweet and chaste...
Buffy: And you made her a vampire.
Angel: First I made her insane. Killed everybody she loved. Visited every mental torture on her I could devise. She eventually fled to a convent, and on the day she took her holy orders, I turned her into a demon.
Buffy: Well. I asked for the truth.
Her First "Surprise"
Buffy: You almost went away today.
Angel: We both did.
Buffy: Angel... I feel like I lost you... You're right, though. We can't be sure of anything.
Angel: Shhh. I...
Buffy: You what?
Angel: I love you. I try not to, but I can't stop.
Buffy: Me, me, too. I can't either.
Angel: Buffy, maybe we shouldn't...
Buffy: Don't. Just kiss me.
Meeting Angelus in "Innocence"
Buffy: Ohhh. Oh, my God! I was freaking out! You just disappeared.
Angelus: What? I took off.
Buffy: But you didn't say anything. You just left.
Angelus: Yeah. Like I really wanted to stick around after that.
Buffy: What?
Angelus: You got a lot to learn about men, kiddo. Although I guess you proved that last night.
Buffy: What are you saying?
Angelus: Let's not make an issue out of it, okay? In fact, let's not talk about it at all. It happened.
Buffy: I, I don't understand. Was it m-me? Was I not good?
Angelus: You were great. Really. I thought you were a pro.
Buffy: How can you say this to me?
Angelus: Lighten up. It was a good time. It doesn't mean like we have to make a big deal.
Buffy: It is a big deal!
Angelus: It's what? Bells ringing, fireworks, a dulcet choir of pretty little birdies? Come on, Buffy. It's not like I've never been there before.
Buffy: Don't touch me.
Angelus: I should've known you wouldn't be able to handle it.
Buffy: Angel! I love you.
Angelus: Love you, too. I'll call you.
Cordy breaks up with Xander in "Bothered ,Bewitched and Bewildered"
Cordelia: Your clothes... You look so good.
Xander: Oh. I let Buffy dress me. Well, not physically.
Cordelia: Perfect. You had to make this harder, didn't you?
Xander: Okay, clearly the fact that I please you visually has got us off on the wrong foot here.
Cordelia: Xander...
Xander: Let me finish. I've been thinking a lot about us lately... the why and the wherefore. You know, once, twice, a kissy here, a kissy there. And you can chalk it all up to hormones. A-and maybe that's all we have here. Tawdry teen lust. But maybe not. Maybe something in you sees something special inside me. And vice versa. I mean, I think I do. See something. So...
Cordelia: Xander... Thank you. It's beautiful. I wanna break up.
Xander: Okay, not quite the reaction I was looking for.
Cordelia: I know. I'm sorry. It's just... Who are we kidding? Even if parts of us do see specialness, we don't fit.
Xander: Yeah! Okay... Do you know what's a good day to break up with somebody? Any day besides Valentine's Day! I mean, what, were you running low on dramatic irony?
Cordelia: I know. I didn't mean to do it this way. I...
Xander: Well, you did.
Buffy in "Passion"
Buffy: I can't hold on to the past anymore. Angel has gone. Nothing's ever gonna bring him back.
She Kisses and Kills Him, "Becoming Pt 2"
Angel: Buffy? What's going on? Where are we? I-I don't remember.
Buffy: Angel?
Angel: You're hurt. Oh, Buffy... God. I... I feel like I haven't seen you in months. Oh, my God, everything's so muddled. I... Oh... Oh, Buffy... What's happening?
Buffy: Shh. Don't worry about it. I love you.
Angel: I love you.
Buffy: Close your eyes.
Angel: Buffy...
I have more a lot more.